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Ellie: I had a slice of ham in my hand. I was going to drop it, so I slapped it hard. It attached itself to the wall
This might kinda count: FF6 Gao. Until you give him a piece of meat he'll randomly appear in battle and runs away if you attack him. Also in Pokemon all the characters in the game except your rival don't usually know you. Final Fantasy Tactics had Rafa and Malak who fought you I think. There's every Guardian Force in FF8 except for like a few. Oh and there's Juhani from Knights.
I guess a version of that was found in tales of symphonia 2 with Lloyd's role as well, although he is more of an extra character later and the reason for his villainous behaviour earlier is kinda lame. And because of the reason, it shouldn't really count.